The BGS digital estimated urban soil chemistry data (GB_EstimatedUrbanSoilChemistry_v3) indicates the estimated geometric mean concentrations (mg kg-1) of Arsenic (As), Cadmium (Cd), Chromium (Cr), Nickel (Ni) and Lead (Pb) in topsoil derived by spatial interpolation of the point source urban soil chemistry data. The information is relevant for the first stage of any assessment of risks to human health required by regulatory authorities in relation to land use and also assessing ecological risks. Estimated topsoil PHE (Potentially Harmful Element) concentrations above respective SGVs (Soil Guideline Value) do not necessarily imply a significant health risk but they do highlight the need to consider whether or not there may be a risk. Comparison of this spatially referenced geochemical data set with information on current or historic land use and geological information might help environmental professionals decide whether high PHE concentrations in topsoils can be attributed to geogenic or anthropogenic sources. The dataset is based on, and limited to, an interpretation of the records in the possession of the BGS at the time the dataset was created. An indication of high estimated PHE concentrations in soil does not necessarily mean that an individual site will have a high PHE concentration. Topsoil concentrations in urban areas are frequently characterised by strong spatial variation over short distances so this data should be interpreted and used with caution. The original urban topsoil samples were collected and analysed as part of the BGS Geochemical Baseline Survey of the Environment (G-BASE) project.